Volume 20, Issue 4 (11-2021)
TB 2021, 20(4): 39-51 |
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Ethics code: IR.SSU.SPH.REC.1398.147
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Dadbinpour A, Shukohifar M, Mozafari Z, Zarei Yazdeli M. Investigating the Relationship between the Vitamin D Status and Depression in Thyroid Patients Referred to Yazd Diabetes Center Clinic in 2020. TB 2021; 20 (4) :39-51
URL: http://tbj.ssu.ac.ir/article-1-3238-en.html
URL: http://tbj.ssu.ac.ir/article-1-3238-en.html
Shahid sadoughi university of medical science , dadbin11@gmail.com
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Evaluation of the efficiency adsorption process with Zeolite@ in the removal of methylene blue dye from aqueous solutions
Negar Einollahzadeh(B.S)1, Mehdi Vosoughi(Ph.D.)2
1. Bachelor of Science of Environmental Health Engineering, Students Research Committee, Ardabil University of Medical Sciences, Ardabil, Iran.
2.Corresponding Author: Assistant professor, Department of Environmental Health Engineering, School of Public Health, Ardabil University of Medical Sciences, Ardabil, Iran. Email: mvn_20@yahoo.com Tel: 09120910243
Abstract
Introduction: Dyes are materials with a complex structure that enter the environment from textile process such as dyeing and washing. The aim of this study was to investigate the efficiency of the absorption process along with adsorption using by Zeolite @ ZnO in the removing methylene blue dye from textile wastewater.
Methods: The structure and morphology of nanoparticles were examined using XRF, FTIR and FESEM techniques. Dye concentrations were determined using a spectrophotometer at 664 nm. In this study, the variables of reaction time, solution pH, adsorbent amount and dye concentration were evaluated. To determine the isotherm and adsorption kinetics, two isotherm models of Langmuir and Freundlich and two kinetics models pseudo-first order pseudo-second order were used.
Results: We found that optimal conditions were concentration of 50 mg/l, adsorbent dose of 1 g/l, pH of 11 and a reaction time of 60 minutes. The removal efficiency under optimal conditions for methylene blue was 95.8%.
Conclusion: The results of the isotherm and adsorption kinetics study for methylene blue showed that the adsorption process follows the Langmuir isotherm and quasi-quadratic kinetics. The maximum adsorption capacity of the adsorbent was determined 384 mg/g using the Langmuir model.
Keywords: Methylene blue, Adsorption, Zeolite@ZnO, Zeolite
Conflict of interest: The authors declared that there is no Conflict interest.
1-Daneshvar N , Salari D , Khataee A . Photocatalytic degradation of azo dye acid red 14 photo in water an ZnO as an altemative catalyst to TiO2. Journal of photochemistry and photobiology.2004; 162(2-3): 317-322. [Persian]
2-Maleki A,Shahmoradi B,rezaei R. Baseline performance combined with hydrogen peroxide and titanium dioxide photochemical method for the removal of Acid Red 18. Journal of kurdistan University of Medical Sciences.2011;101-8. [Persian]
3-Ngah WW, Teong LC, Hanafiah MM. Adsorption of dyes and heavy metal ions by chitosan composites. Carbohyd Polym.2011;83:1446–56.
4- Karimi A , Mahdizadeh F, Eskandarian M. Enzymatic in-situ generation of H2O2 for decolorization of Acid Blue 113 by fenton process. Chemical Industry and Chemical Engineering Quarterly/CICEQ .2012;18(1):89-94.[Persian]
5- Ghodbane H, Hamdaoui O. Intensification of sonochemical decolorization of anthraquinonic dye Acid Blue 25 using carbon tetrachloride. Ultrasonics Sonochemistry.2009 ;16(4):455-61.
6-Li M, Li JT, Sun HW. Sonochemical decolorization of acid black 210 in the presence of exfoliated graphite,Ultrasonics Sonochemistry.2008 ;15(1):37-42.
7- Peng X, Hu X, Fu D,et al. Adsorption removal of acid black 1 from aqueous solution using ordered mesoporous carbon. Applied surface science.2014;294:71-80.
8-Falah H. Comparison between solar and artificial photocatalytic decolorization of textile industrial wastewater. International Journal of Photoenergy.2012.[Persian]
9-Taran M,Sharifi M, Bagheri S. Utilization of textile wastewater as carbon source by newly isolated Haloarcula sp. IRU1: optimization of conditions by Taguchi methodology. Clean Technologies and Environmental Policy.2011; 13(3): 535-8. [Persian]
10-Shah MP. Microbial degradation of textile dye (Remazol Black B) by Bacillus spp. ETL-2012. Journal of Bioremediation and Biodegradation.2013;4(2) :6-11
11-Rafatullah M, Sulaiman O, Hashim R, et al. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of hazardous materials.2010; 177(1-3): 70-80.
12-Ponnusami V, Madhuram R, Krithika V, et al. Effects of process variables on kinetics of methylene blue sorption onto untreated guava (Psidium guajava) leaf powder: Statistical analysis. Chemical Engineering Journal.2008;140(1-3): 609-613.
13-Parsa JB, Vahidian HR, Soleymani AR, et al. Removal of Acid Brown 14 in aqueous media by electrocoagulation: Optimization parameters and minimizing of energy consumption. Desalination.2011; 278(1): 295-302.[Persian]
14-Martínez SS, Uribe EV. Enhanced sonochemical degradation of azure B dye by the electroFenton process. Ultrasonics sonochemistry.2012; 19(1):174-8.
15-Hu QH, Qiao SZ, Haghseresht F,et al. Adsorption Study for Removal of Basic Red Dye Using Bentonite. Industrial & Engineering Chemistry Research.2006; 45(2): 733-8.
16- Ghaedi M, Ghayedi M, Kokhdan SN, et al. Palladium, silver, and zinc oxide nanoparticles loaded on activated carbon as adsorbent for removal of bromophenol red from aqueous solution. Journal of Industrial and Engineering Chemistry.2013;19(4): 1209-17. [Persian]
17-Fazlzadeh M, Khosravi R, Zarei A. Green synthesis of zinc oxide nanoparticles using Peganum harmala seed extract, and loaded on Peganum harmala seed powdered activated carbon as new adsorbent for removal of Cr (VI) from aqueous solution. Ecological Engineering.2017;103: 180-90. [Persian]
18- Ramezani F, Kazemi B, Jebali A.Biosynthesis of silver nanoparticles by Leishmania sp. New Cellular & Molecular Biotechnology journal.2013; 3(9): 107-11. [Persian]
19- Santhoshkumar J, Kumar SV, Rajeshkumar S. Synthesis of zinc oxide nanoparticles using plant leaf extract against urinary tract infection pathogen. Resource-Efficient Technologies.2017; 3(4): 459-65.
20- Lohrasbi S, Kouhbanani MA, Beheshtkhoo N,et al .Green synthesis of iron nanoparticles using plantago major leaf extract and their application as a catalyst for the decolorization of azo dye. Bio Nano Science.2019 ;9(2): 317-22.[Persian]
21-Muzaffar S, Tahir H. Enhanced synthesis of silver nanoparticles by combination of plants extract and starch for the removal of cationic dye from simulated waste water using response surface methodology. Journal of Molecular Liquids.2018; 252: 368-82. [Persian]
22- Rafique M, Sadaf I, Tahir MB, et al. Novel and facile synthesis of silver nanoparticles using Albizia procera leaf extract for dye degradation and antibacterial applications. Materials Science and Engineering: C 2019; 99: 1313-1324.
23- Ma J, Yu F, Zhou L, Jin L, Yang M, Luan J, Tang Y, Fan H, Yuan Z, Chen J. Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes. ACS applied materials & interfaces.2012 ;4(11):5749-60.
24-Rashtbari Y, Hazrati S, Afshin S, et al. Data on cephalexin removal using powdered activated carbon (PPAC) derived from pomegranate peel. Data in brief .2018;20:1434-39. ]Persion[
25- Afshin S, Mokhtari SA, Vosoughi M, et al. Data of adsorption of Basic Blue 41 dye from aqueous solutions by activated carbon prepared from filamentous algae. Data in brief.2018; 21:1008-13. ]Persion[
26-Maleki A, Mahvi AH, Rezaee R, etal. Removal of reactive blue 19 using natural and modified zeolites. Iranian Journal of Health and Environment.2013; 5(4):519-30.]Persion[
27-Kuzniarska-Biernacka I , Fonseca AM , Neves IC. Manganese complexes with triazenido ligands encapsulated in NaY zeolite as heterogeneous catalysts. Inorganica Chimica Acta.2013; 394: 591-7.
28- Gong R, Zhu S, Zhang D, et al. Adsorption behavior of cationic dyes on citric acid esterifying wheat straw: kinetic and thermodynamic profile. Desalination.2008 ; 230(1-3): 220-8.
29 Ai L, Zhang C, Liao F,et al. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. Journal of hazardous materials .2011;198:282-90.
30-Anbia M , Hariri S A . Removal of methylene blue from aqueous solution using nanoporous SBA-3. Desalination.2010; 261(1-2): 61-66.
31- Yu S, Liu M, Ma M, et al. Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes. Journal of Membrane Science.2010; 350(1-2):83-91.
32-Pavan FA, Mazzocato AC, Gushikem Y. Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent. Bioresource technology.2008; 99(8):3162-5.
33-ALzaydien A. Adsorption of methylene blue from aqueous solution onto a low-cost natural Jordanian Tripoli. American Journal of Applied Sciences.2009;6(6): 1047.
34-Allegre C, Moulin P, Maisseu M, et al. Treatment and reuse of reactive dyeing effluents. Journal of Membrane Science.2006;269(1-2):15-34.
35-Nevine Kamal A. Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination.2008 ; 223(1-3): 152-61.]Persion[
36- Cengiz S, Cavas L. Removal of methylene blue by invasive marine seaweed: Caulerpa racemosa var. cylindracea. Bioresource Technology2008; 99(7): 2357-2363.
37- Gil A, Assis FC, Albeniz S, et al. Removal of dyes from wastewaters by adsorption on pillared clays. Chemical Engineering Journal.2011;168(3):1032-40.
38-Kushwaha , Kumar A, Gupta N, et al. Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society.2014; 18(3):200-7.
39- Shokohi, Purfarzi, SHirzad sibni ,et al. Removal of Reactive Black 5 (RB5) dye from aquatic solution by using of adsorption onto synthesized sodium alginate magnetic beads.2011;4(1) 1-10.[Persian]
40-Khattri SD, Singh MK. Removal of malachite green from dye wastewater using neem sawdust by adsorption. Journal of hazardous materials.2009;167(1-3):1089-94.
41-Biglari H, RodrigueziCouto S, Omidi Khaniabadi Y, Nourmorad H ,et al. Cationic surfactant-modified clay as an adsorbent for the removal of synthetic dyes from aqueous solutions. International journal of chemical reactor engineering.2018; 16(5):1044-48.]Persion[
42-Golestanifar H, Asadi A, Alinezhad A, et al. Isotherm and kinetic studies on the adsorption of nitrate onto nanoalumina and iron-modified pumice. Desalination and Water Treatment.2016; 57(12): 5480-87.]Persion[
Negar Einollahzadeh(B.S)1, Mehdi Vosoughi(Ph.D.)2
1. Bachelor of Science of Environmental Health Engineering, Students Research Committee, Ardabil University of Medical Sciences, Ardabil, Iran.
2.Corresponding Author: Assistant professor, Department of Environmental Health Engineering, School of Public Health, Ardabil University of Medical Sciences, Ardabil, Iran. Email: mvn_20@yahoo.com Tel: 09120910243
Abstract
Introduction: Dyes are materials with a complex structure that enter the environment from textile process such as dyeing and washing. The aim of this study was to investigate the efficiency of the absorption process along with adsorption using by Zeolite @ ZnO in the removing methylene blue dye from textile wastewater.
Methods: The structure and morphology of nanoparticles were examined using XRF, FTIR and FESEM techniques. Dye concentrations were determined using a spectrophotometer at 664 nm. In this study, the variables of reaction time, solution pH, adsorbent amount and dye concentration were evaluated. To determine the isotherm and adsorption kinetics, two isotherm models of Langmuir and Freundlich and two kinetics models pseudo-first order pseudo-second order were used.
Results: We found that optimal conditions were concentration of 50 mg/l, adsorbent dose of 1 g/l, pH of 11 and a reaction time of 60 minutes. The removal efficiency under optimal conditions for methylene blue was 95.8%.
Conclusion: The results of the isotherm and adsorption kinetics study for methylene blue showed that the adsorption process follows the Langmuir isotherm and quasi-quadratic kinetics. The maximum adsorption capacity of the adsorbent was determined 384 mg/g using the Langmuir model.
Keywords: Methylene blue, Adsorption, Zeolite@ZnO, Zeolite
Conflict of interest: The authors declared that there is no Conflict interest.
1-Daneshvar N , Salari D , Khataee A . Photocatalytic degradation of azo dye acid red 14 photo in water an ZnO as an altemative catalyst to TiO2. Journal of photochemistry and photobiology.2004; 162(2-3): 317-322. [Persian]
2-Maleki A,Shahmoradi B,rezaei R. Baseline performance combined with hydrogen peroxide and titanium dioxide photochemical method for the removal of Acid Red 18. Journal of kurdistan University of Medical Sciences.2011;101-8. [Persian]
3-Ngah WW, Teong LC, Hanafiah MM. Adsorption of dyes and heavy metal ions by chitosan composites. Carbohyd Polym.2011;83:1446–56.
4- Karimi A , Mahdizadeh F, Eskandarian M. Enzymatic in-situ generation of H2O2 for decolorization of Acid Blue 113 by fenton process. Chemical Industry and Chemical Engineering Quarterly/CICEQ .2012;18(1):89-94.[Persian]
5- Ghodbane H, Hamdaoui O. Intensification of sonochemical decolorization of anthraquinonic dye Acid Blue 25 using carbon tetrachloride. Ultrasonics Sonochemistry.2009 ;16(4):455-61.
6-Li M, Li JT, Sun HW. Sonochemical decolorization of acid black 210 in the presence of exfoliated graphite,Ultrasonics Sonochemistry.2008 ;15(1):37-42.
7- Peng X, Hu X, Fu D,et al. Adsorption removal of acid black 1 from aqueous solution using ordered mesoporous carbon. Applied surface science.2014;294:71-80.
8-Falah H. Comparison between solar and artificial photocatalytic decolorization of textile industrial wastewater. International Journal of Photoenergy.2012.[Persian]
9-Taran M,Sharifi M, Bagheri S. Utilization of textile wastewater as carbon source by newly isolated Haloarcula sp. IRU1: optimization of conditions by Taguchi methodology. Clean Technologies and Environmental Policy.2011; 13(3): 535-8. [Persian]
10-Shah MP. Microbial degradation of textile dye (Remazol Black B) by Bacillus spp. ETL-2012. Journal of Bioremediation and Biodegradation.2013;4(2) :6-11
11-Rafatullah M, Sulaiman O, Hashim R, et al. Adsorption of methylene blue on low-cost adsorbents: a review. Journal of hazardous materials.2010; 177(1-3): 70-80.
12-Ponnusami V, Madhuram R, Krithika V, et al. Effects of process variables on kinetics of methylene blue sorption onto untreated guava (Psidium guajava) leaf powder: Statistical analysis. Chemical Engineering Journal.2008;140(1-3): 609-613.
13-Parsa JB, Vahidian HR, Soleymani AR, et al. Removal of Acid Brown 14 in aqueous media by electrocoagulation: Optimization parameters and minimizing of energy consumption. Desalination.2011; 278(1): 295-302.[Persian]
14-Martínez SS, Uribe EV. Enhanced sonochemical degradation of azure B dye by the electroFenton process. Ultrasonics sonochemistry.2012; 19(1):174-8.
15-Hu QH, Qiao SZ, Haghseresht F,et al. Adsorption Study for Removal of Basic Red Dye Using Bentonite. Industrial & Engineering Chemistry Research.2006; 45(2): 733-8.
16- Ghaedi M, Ghayedi M, Kokhdan SN, et al. Palladium, silver, and zinc oxide nanoparticles loaded on activated carbon as adsorbent for removal of bromophenol red from aqueous solution. Journal of Industrial and Engineering Chemistry.2013;19(4): 1209-17. [Persian]
17-Fazlzadeh M, Khosravi R, Zarei A. Green synthesis of zinc oxide nanoparticles using Peganum harmala seed extract, and loaded on Peganum harmala seed powdered activated carbon as new adsorbent for removal of Cr (VI) from aqueous solution. Ecological Engineering.2017;103: 180-90. [Persian]
18- Ramezani F, Kazemi B, Jebali A.Biosynthesis of silver nanoparticles by Leishmania sp. New Cellular & Molecular Biotechnology journal.2013; 3(9): 107-11. [Persian]
19- Santhoshkumar J, Kumar SV, Rajeshkumar S. Synthesis of zinc oxide nanoparticles using plant leaf extract against urinary tract infection pathogen. Resource-Efficient Technologies.2017; 3(4): 459-65.
20- Lohrasbi S, Kouhbanani MA, Beheshtkhoo N,et al .Green synthesis of iron nanoparticles using plantago major leaf extract and their application as a catalyst for the decolorization of azo dye. Bio Nano Science.2019 ;9(2): 317-22.[Persian]
21-Muzaffar S, Tahir H. Enhanced synthesis of silver nanoparticles by combination of plants extract and starch for the removal of cationic dye from simulated waste water using response surface methodology. Journal of Molecular Liquids.2018; 252: 368-82. [Persian]
22- Rafique M, Sadaf I, Tahir MB, et al. Novel and facile synthesis of silver nanoparticles using Albizia procera leaf extract for dye degradation and antibacterial applications. Materials Science and Engineering: C 2019; 99: 1313-1324.
23- Ma J, Yu F, Zhou L, Jin L, Yang M, Luan J, Tang Y, Fan H, Yuan Z, Chen J. Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes. ACS applied materials & interfaces.2012 ;4(11):5749-60.
24-Rashtbari Y, Hazrati S, Afshin S, et al. Data on cephalexin removal using powdered activated carbon (PPAC) derived from pomegranate peel. Data in brief .2018;20:1434-39. ]Persion[
25- Afshin S, Mokhtari SA, Vosoughi M, et al. Data of adsorption of Basic Blue 41 dye from aqueous solutions by activated carbon prepared from filamentous algae. Data in brief.2018; 21:1008-13. ]Persion[
26-Maleki A, Mahvi AH, Rezaee R, etal. Removal of reactive blue 19 using natural and modified zeolites. Iranian Journal of Health and Environment.2013; 5(4):519-30.]Persion[
27-Kuzniarska-Biernacka I , Fonseca AM , Neves IC. Manganese complexes with triazenido ligands encapsulated in NaY zeolite as heterogeneous catalysts. Inorganica Chimica Acta.2013; 394: 591-7.
28- Gong R, Zhu S, Zhang D, et al. Adsorption behavior of cationic dyes on citric acid esterifying wheat straw: kinetic and thermodynamic profile. Desalination.2008 ; 230(1-3): 220-8.
29 Ai L, Zhang C, Liao F,et al. Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis. Journal of hazardous materials .2011;198:282-90.
30-Anbia M , Hariri S A . Removal of methylene blue from aqueous solution using nanoporous SBA-3. Desalination.2010; 261(1-2): 61-66.
31- Yu S, Liu M, Ma M, et al. Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes. Journal of Membrane Science.2010; 350(1-2):83-91.
32-Pavan FA, Mazzocato AC, Gushikem Y. Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent. Bioresource technology.2008; 99(8):3162-5.
33-ALzaydien A. Adsorption of methylene blue from aqueous solution onto a low-cost natural Jordanian Tripoli. American Journal of Applied Sciences.2009;6(6): 1047.
34-Allegre C, Moulin P, Maisseu M, et al. Treatment and reuse of reactive dyeing effluents. Journal of Membrane Science.2006;269(1-2):15-34.
35-Nevine Kamal A. Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination.2008 ; 223(1-3): 152-61.]Persion[
36- Cengiz S, Cavas L. Removal of methylene blue by invasive marine seaweed: Caulerpa racemosa var. cylindracea. Bioresource Technology2008; 99(7): 2357-2363.
37- Gil A, Assis FC, Albeniz S, et al. Removal of dyes from wastewaters by adsorption on pillared clays. Chemical Engineering Journal.2011;168(3):1032-40.
38-Kushwaha , Kumar A, Gupta N, et al. Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society.2014; 18(3):200-7.
39- Shokohi, Purfarzi, SHirzad sibni ,et al. Removal of Reactive Black 5 (RB5) dye from aquatic solution by using of adsorption onto synthesized sodium alginate magnetic beads.2011;4(1) 1-10.[Persian]
40-Khattri SD, Singh MK. Removal of malachite green from dye wastewater using neem sawdust by adsorption. Journal of hazardous materials.2009;167(1-3):1089-94.
41-Biglari H, RodrigueziCouto S, Omidi Khaniabadi Y, Nourmorad H ,et al. Cationic surfactant-modified clay as an adsorbent for the removal of synthetic dyes from aqueous solutions. International journal of chemical reactor engineering.2018; 16(5):1044-48.]Persion[
42-Golestanifar H, Asadi A, Alinezhad A, et al. Isotherm and kinetic studies on the adsorption of nitrate onto nanoalumina and iron-modified pumice. Desalination and Water Treatment.2016; 57(12): 5480-87.]Persion[
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Received: 2021/08/2 | Accepted: 2021/10/4 | Published: 2021/11/1
Received: 2021/08/2 | Accepted: 2021/10/4 | Published: 2021/11/1
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